Beilstein J. Org. Chem.2024,20, 479–496, doi:10.3762/bjoc.20.43
further (see Supporting Information File 1, Figure S19). This comparison reveals that the Jackiephos supported gold accelerates the reaction more than (PhO)P(o-biphenyl)2 does, although this may be in part an anioneffect [7]. The bis(trifluoromethyl)aryl substituent is expected to be more electron
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Graphical Abstract
Scheme 1:
Proposed mechanism and observation of alkylgold intermediates.
Beilstein J. Org. Chem.2015,11, 42–49, doi:10.3762/bjoc.11.7
copolymerisation reaction.
Keywords: anioneffect; carbon dioxide; CO2 chemistry; copolymerisation; polyethercarbonate; zinc catalyst; Introduction
The fixation of carbon dioxide (CO2) into polymers [1][2][3] provides highly promising options for the utilization of CO2 [4][5][6][7]. The copolymerisation of CO2
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Graphical Abstract
Scheme 1:
Structural motif of two important types of catalysts and typical substrate specificity in the copol...